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DKL Engineering, Inc.
		
Handbook of Sulphuric Acid Manufacturing
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Preface
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Acid Plant Database October 29, 2019
| Owner | 
	Freeport-McMoRan Copper & Gold Inc. Phelps Dodge  | 
    
  | 
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| Location | 
	Miami, Arizona USA  | 
  |||
| Background | 
	Formerly
     - Inspiration Consolidated Copper Company - Cyprus Amax Minerals Company - 1999 Phelps Dodge acquires Cyprus - 2007 Phelps Dodge acquired by Freeport-McMoRan  | 
  |||
| Website | 
	www.fcx.com  www.phelpsdodge.com  | 
  |||
| Plant | Miami Smelter | |||
| Coordinates | 33º 24' 52" N, 110º 51' 30" W | |||
| Type of Plant | Metallurgical | |||
| Gas Source | 
	Copper IsaSmelt technology (primary furnace)(1991). Four Hoboken style converters One Inspiration converter  | 
  |||
| Plant Capacity | - | |||
| SA/DA | 3/1 DA | |||
| Emissions | 
	SO2: < 650 ppmv, < 820 lb/h, 3515 ton/a Opacity: < 20% NOx: < 97.5 lb/h, < 425 tons/a  | 
  |||
| Status | Operating | |||
| Year Built | 1972 | |||
| Technology | Lurgi - Outotec | |||
| Contractor | - | |||
| Remarks | 
	1995 - Rehabilitation of the contact and strong acid sections begin 2006 - Revamp of gas cleaning system  | 
  |||
| Permits | 
	Arizona Department of Environmental Quality  
	www.azdeq.gov
     Facility ID: Air Quality Class I Permit  | 
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| Permit No. | Issue Date | Expiry Date | Details | |
| 0310-84 | August 1, 1984 | - | Operating Permit | |
| 1232 | May 30, 1991 | - | Installation of IsaSmelt | |
| 1000340 | May 30, 1996 | - | Revision to Permit 1232 | |
| 1000266 | December 24, 1997 | - | - | |
| 1000046 | June 26, 2002 | - | - | |
| Pictures |     | 
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| General | 
	
	The plant’s smelter was modernized in 1974 to meet 
	Clean Air Act standards The smelter is the only one in the United States to achieve International Organization for Standardization (ISO) 9001:2000 certification. In addition to copper concentrates, the smelter also recycles inorganic metal-bearing waste typically produced by high technology industries, extending the useful life of valuable metals and reducing disposal of metal-bearing waste in landfills. Copper and other precious metals are extracted during this process. In addition, the smelter produces by-product sulfuric acid.  | 
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| References | -Jones, D.M., Brandt, R., Nanda, A. and Piatkiewicz, A., "Environmental Upgrade at the Freeport McMoRan Miami Smelter", Copper 2019, Vancouver, Canada. | |||
| News | 
	September 20, 2017 - It is happening tomorrow night 
	(Thursday September 21st ) in the Miami Town Hall beginning 6pm.  This is 
	when the Arizona Department of Environmental Quality will be holding a 
	public hearing on its plans to issue a Renewal Permit for the continued 
	operations  of Freeport McMoRan’s copper smelter near Miami.  It was 
	back in 2014 when Freeport announced it was planning a major smelter 
	expansion project at its Miami operations which the company said would 
	increase copper production and also comply with new tougher EPA standard.  
	The company went on to say upon completion of the project the copper 
	concentrate throughput for the Miami smelter would increase by approximately 
	30 percent to a capacity of 900,000 tons per year from the current average 
	during this period of time which was some 700,000 tons per year.  
	According to the Arizona Silver Belt  the expanded smelter capabilities 
	 would comply with the new EPA ambient air quality standards for sulfur 
	dioxide emissions.  In further details about the copper smelter 
	expansion project here a major component of the expansion was to install a 
	new smelting vessel which along with modifications to other facilities in 
	the smelter was to allow for increased copper production.  The local 
	press was also told much of the construction work would be related to 
	emission control systems in order to  capture virtually all fugitive gases 
	and particulate emissions. The expected result would be  the capture of over 
	99 percent of the sulfur dioxide and other emissions from the Miami 
	operations.  The new smelting vessel was scheduled to be commissioned 
	in the second quarter of this year ( 2017 ) with production ramping up 
	shortly thereafter.  Up to several hundred construction workers were 
	involved in the expansion. The company said it had plans to hire about 20 
	new employees to operate and maintain the new emission control systems and 
	facilities.  To feed the expanded smelter here additional copper 
	concentrate was to come primarily from Freeport’,s mines at Morenci, Arizona 
	and Chino , New Mexico.  Concentrate would continue to be coming in from the 
	company’s Serrita and Bagdad Arizona mines.  Interested persons who 
	plan to go to the public hearing tomorrow night still have time to view the 
	ADEQ’s Draft Renewal of the Smelter Permit and other documentation which are 
	available for inspection at  the Miami Town Hall during regular business 
	hours  at 500 Sullivan Street in the Town of Miami.  Or this paper work can 
	be reviewed directly from the ADEQ web site.  Oral and written comments will 
	be taken from the public by representatives of the  Arizona Department of 
	Environmental Quality.  Grounds for comment are limited to whether the draft 
	of the agency’s smelter permit renewal meets criteria for issuance spelled 
	out in the state air pollution control laws or rules. October 11, 2014 - The Hayden smelter, one of whose stacks stands about 1,000 feet tall, has been a fixture in the community since starting operations in 1912. With slightly more than 600 people working at Asarco’s Hayden operation, it’s by far the biggest employer in a town of fewer than 1,000 permanent residents. In 2013, the Hayden smelter produced about 273 million tons of copper and 490,000 tons of sulfuric acid, and paid about $54 million in salaries and wages, the Arizona Mining Association told a state House committee in August. The Freeport smelter in Miami, operating since 1915, employs about 1,000 people. It produces about 420 million pounds of copper and 725,000 tons of sulfuric acid annually, the association said. The Hayden smelter has also been a continuing source of controversy over the past 15 years, with many of its neighbors saying it has damaged their health. Asarco has upgraded the smelter many times since it first opened in 1912. But since the middle 2000s, the Hayden area has been under federal investigation under the EPA’s Superfund toxic waste cleanup program. In 2002, for instance, more than 250 current and former residents of Hayden and nearby Winkelman, Kearny and Riverside signed class-action lawsuits, alleging that Asarco’s toxic releases had injured them, contaminated the environment, and devalued their homes. The company wouldn’t comment directly, but officials said studies by the University of Arizona and the University of Pittsburgh found no connection between smelter operations and illness. The suit was later settled for $4.8 million. In 2008 and 2009, Asarco spent $13.5 million to remove contaminated soil from 265 yards in Hayden under regulators’ oversight.  | 
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MTPD - Metric Tonne per Day           
STPD - Short Ton per Day
MTPA - Metric Tonne per Annum      STPA - Short Ton per 
Annum
SA - Single Absorption
DA - Double Absorption  
* Coordinates can be used to 
locate plant on Google Earth