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Acid Plant Database April 11, 2017
Owner | Tesoro Refining & Marketing Co. | |||
Location | 150
Solano Way Martinez, California USA 94553-1465 |
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Background | At the end of 2001, Valero Energy Corporation acquired Ultramar Diamond Shamrock Corporation with sulfuric acid plants in refineries at Dumas (McKee refinery), Tex. ; Wilmington , Calif. and Martinez , Calif. Valero then sold the Martinez refinery to Tesoro Petroleum in May, 2002. | |||
Website | www.tsocorp.com | |||
Plant | Golden Eagle Refinery | |||
Coordinates | 38º 1' 29" N, 122º 3' 25" W | |||
Type of Plant | Acid Regeneration | |||
Gas Source |
Alkylation Waste Acid Hydrogen Sulphide Gas |
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Plant Capacity |
435.4 MTPD (480 STPD) 158,939 MTPA (175200 STPA) (365 d/a) |
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SA/DA | 3/1 DA | |||
Emissions |
SO2: < 300 ppm @ 12% O2 Acid Mist: 0.15 g/kg (0.3 lb/ton) Opacity: Ringlemann No. 1 |
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Status | Operating | |||
Year Built | - | |||
Technology | - | |||
Contractor | - | |||
Remarks | - | |||
Permits |
State of California, Bay Area Air Quality Management District
www.baaqmd.gov Facility ID: B2758 |
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Permit No. |
Issue Date | Expiry Date | Date Modified | |
B2758 | March 20, 2008 | - | - | |
Pictures | ||||
General | Plant is located next to MECS catalyst manufacturing site. | |||
References | - | |||
News |
March 12, 2017 - On February 12,
2014, an incident occurred at the Tesoro Refinery in Martinez, which burned
two workers and released an estimated 84,000 pounds of sulfuric acid. Less
than a month later, on March 10, 2014, sulfuric acid sprayed and burned two
contract workers during the removal of piping. Both incidents occurred in
the refinery’s alkylation unit – where high-octane blending components are
produced for gasoline.
Chairperson Vanessa Allen Sutherland said, “The CSB urges all refineries to review the key findings and conclusions of the board’s case study and to apply those learnings to their own facilities. It is imperative that companies continually work towards improving their operations in an effort to prevent future incidents and ensure the safety of their workforce.” The CSB’s case study examines the Tesoro Martinez Refinery through the evaluation of previous incidents, worker statements, gaps in safety standards, deviations from established procedures and practices, and past efforts to assess and strengthen site safety culture. The investigation found a number of safety culture concerns at the refinery, such as: o Characterization of the February 2014 incident as a minor injury while the incident should have been classified as the most serious type of process safety incident under industry guidelines; o Exposure of alkylation unit workers to hazardous materials including vapors, acids, and corrosives; o Removal of safer sulfuric acid sampling systems from service and reliance on inadequate temporary alkylation unit equipment; o Failure to provide alkylation unit workers with necessary protective equipment; o Existence of site-specific safety policies that were less protective than corporate policies and established industry good practice; o Failure to develop an action plan to address concerns identified in a 2007 safety culture survey; o Withdrawal from key national safety programs that workers believed were effective; and o Perceived pressure on alkylation unit workers to expedite training and reduce cost. The state of California has issued a draft refinery process safety management standard containing more rigorous safety regulations for the oversight of petroleum refineries, and the CSB is encouraged by these proactive changes to improve safety for workers and communities. The CSB’s case study underscores the need for the proposed refinery safety reforms as well as individual refineries to continually assess and improve their process safety programs. The CSB’s case study emphasizes that regulators can use what are known as lagging process safety indicators, such as spills, fires, or gas releases, as well as leading indicators such as timely maintenance on safety critical equipment to focus inspections, audits, and timely closure of action items resulting from incident investigations to help drive process safety improvement. “The continued recurrence of sulfuric acid incidents demonstrates the need for improvements at the Tesoro refinery. We recommend that the refinery report process safety indicators to the regulator, said Lead Investigator Dan Tillema. “Regulators should monitor these indicators and conduct preventive inspections that lead to corrective actions –this is a critical component of an effective safety program – the ultimate goal is to ensure that risk is continually reduced.” www.satprnews.com July 18, 2016 - Oil company Tesoro Corp. and its subsidiaries have agreed to purchase eco-friendly, low-emission buses for a Contra Costa County school district as part of a big nationwide settlement over alleged air pollution, federal officials announced Monday.The total $425 million payout by Tesoro and Par Hawaii Refining — which acquired its refinery on Oahu from Tesoro in 2013 — follows accusations of Clean Air Act violations at six refineries, including the Martinez Refinery, according to the Environmental Protection Agency and the Department of Justice.Under the legal agreement, Tesoro will spend $24 million to better control leaks, flaring and other sources of harmful emissions at the Bay Area plant as well as pay $1 million for the replacement of old diesel buses at the Mount Diablo Unified School District. The four or more new buses will run on compressed natural gas, reducing particulate matter and greenhouse gases spewed into the air.“EPA remains committed to ensuring companies take responsibility for protecting public health and the environment,” said Alexis Strauss, the agency’s acting regional administrator, in a statement. Nationwide, the settlement calls for $403 million in new pollution-control equipment at refineries in Alaska, Hawaii, North Dakota, Utah, Washington and California. The upgrades are expected to cut the annual emission of sulfur dioxide by 773 tons, nitrogen oxides by 407 tons and volatile organic compounds by 1,140 tons.Tesoro will also pay a civil penalty of $10.5 million, the EPA said.The company has a record of run-ins with air quality regulators at its Martinez plant. Within the past year, Tesoro has twice agreed to pay to settle charges of pollution at the facility for a cumulative $4.5 million. The latest allegations include problems with the refinery’s coker unit, fluid catalytic cracking unit, sulfuric acid plant, sulfur pit and flaring operations. Tesoro officials said in an email that most of the upgrades required under the settlement have been completed or are under way. The company did not admit liability in the alleged violations.
August 19, 2014 - In a report published last Friday, the US
Chemical Safety Board (CSB) said that loose pipe fittings caused the 84,000
pound sulfuric acid spill that seriously injured two workers at Tesoro’s
Golden Eagle refinery on February 12.
Golden Eagle is located in Martinez, California, about 35 mile
northwest of San Francisco. The
report was prepared by California engineering and laboratory testing firm
Anamet Inc. The report details
findings from an examination of a stainless-steel tube assembly recovered
from the accident site by the California Division of Occupational Safety and
Health (Cal/OSHA). The report
said that the tubes and a compression joint at the sulfuric acid sampling
station were not sufficiently tightened during installation.
The tubes were shaken loose from the compression joint when they were
pressurized. Cal/OSHA closed
down the Golden Eagle alkylation unit from February 18 to 28.
Employees told Cal/OSHA that they had been afraid to work in the unit
before the accident because of safety concerns.
“This incident highlights the need for strong process safety
management at facilities that ensures mechanical integrity is verified prior
to the introduction of hazardous chemicals into equipment,” CSB Chairperson
Rafael Moure-Eraso said.
Moure-Eraso said the need for safety management is pressing because of
another sulfuric acid spill at the same refinery on March 10.
Two contract workers were sprayed with sulfuric acid while conducting
planned maintenance during that incident.
“Four workers burned by sulfuric acid in less than a month clearly
demonstrates there are significant opportunities within the refinery for
improvement in safety performance,” Moure-Eraso said.
Cal/OSHA is continuing a separate investigation at the refinery,
focusing on the refinery’s mechanical integrity and operating procedures.
The Golden Eagle refinery has a crude oil capacity of 166,000 barrels
per day and employees 650 people.
San-Antonio based Tesoro is an independent downstream company. March 10, 2014 - On 12 February, two workers at the Golden Eagle (GE) plant owned by Tesoro Corporation in Martinez, California suffered severe facial burns early in the morning after a pipe containing sulfuric acid burst, spraying acid. After being airlifted by helicopter to a hospital in Sacramento, California, the two received treatment for first-and second-degree facial burns. They were released that day. The next day, CEO Gregory Goff forced three US Chemical Safety Board (CSB) investigators to leave after Tesoro’s lawyers raised “jurisdictional challenges.” Although Tesoro eventually allowed investigators back on site on February 28, the location of the accident was already back in production, hindering any investigation. CSB’s three-member board is alleging several violations of federal law governing safety at GE, including “refusing to permit the CSB to return to the site, refusing to preserve the site, prohibiting the conduct of certain interviews and indicating [non-compliance] with a duly issued document subpoena.” The GE refinery, also known as the Avon refinery, produces motor fuels, such as cleaner burning California Air Resources Board (CARB) gasoline and CARB diesel fuel, as well as conventional gasoline and diesel fuel. According to its web site, the GE refinery employs 700 full-time workers and produces 166,000 barrels per day. It is the second largest refinery in Northern California and is only one of many oil refineries that the Fortune 100 company, Tesoro, operates. Tesoro is the 24th largest source of air pollution in the United States, releasing roughly 3,740,000 lb (1,700 t) of toxic chemicals annually into the air. The Environmental Protection Agency named Tesoro as the culprit in the creation of four Superfund or Comprehensive Environmental Response, Compensation, and Liability Act toxic waste sites, all of which have destroyed the surrounding environment. |
MTPD - Metric Tonne per Day
STPD - Short Ton per Day
MTPA - Metric Tonne per Annum STPA - Short Ton per
Annum
SA - Single Absorption
DA - Double Absorption
* Coordinates can be used to
locate plant on Google Earth