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Sulphuric Acid on the WebTM Technical Manual DKL Engineering, Inc.

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Sulphuric Acid - NEWS


Updated May 4, 2016

 

2016

PQ Corporation Announces Closing of Merger With Eco Services Operations LLC

Etihad Rail transports 5m tonnes of sulphur granules

Smelter Fire Secrecy

Geingob opens N$3 billion sulphuric plant in Tsumeb
Calabrian Corp. to begin public consultation on Timmins sulphur dioxide plant

Outotec Awardeda Sulphuric Acid Plant Contract from Boliden Harjavalta

Sulphur dioxide levels exceed maximum limit 

The Mar Camino solution 

Technip to provide Dorr roaster system for KGHM’s Polish copper smelter project

Gecko’s Big Ambitions
Abuse of dominant position – commission issues statement of objection 
King Mohammed VI Inaugurates MAD 6.1 billion OCP Projects 


2015   2014   2013   2012   2011   2010   2009   2008   2007   2006   2005    2004   2003    2002   2001    2000   1999    1998

 

PQ Corporation Announces Closing of Merger With Eco Services Operations LLC

May 4, 2016 - PQ Corporation (“PQ”), a leading global manufacturer of specialty inorganic performance chemicals, high-end catalysts, and engineered glass beads, and Eco Services Operations LLC (“Eco Services”), the North American leader in sulfuric acid recycling services, announced today the closing of a previously announced merger that bolsters PQ’s position as a world-class specialty inorganic chemical company.  Concurrently with the closing of the merger between PQ and Eco Services, PQ has also refinanced its existing credit facilities by entering into a USD$1.2 billion senior secured term loan (consisting of a USD$900 million senior secured term loan and a USD$300 million Euro equivalent senior secured term loan), USD$625 million in new senior secured notes, USD$525 million in senior unsecured notes, and a USD$200 million asset-based secured revolving credit facility. The existing $200 million of Eco Services notes will remain outstanding.“Combining PQ and Eco Services and refinancing our credit facilities positions the new PQ to grow and prosper well into the future,” said George J. Biltz, President and Chief Executive Officer of the combined company. “Moving forward, our customers will continue to see superior product offerings and top-notch service from our dedicated team.”Biltz also noted that the combination joins two specialty inorganic chemical companies that have similar business models and complementary customers. Both companies provide mission-critical products and services to the refinery industry, with PQ supplying catalysts necessary for the refining of crude oil and Eco Services providing sulfuric acid regeneration services needed in the alkylation process. Biltz anticipates a smooth integration process that is expected to yield significant back-office savings and other synergies that will serve PQ’s growth initiatives.Michael R. Boyce will continue to serve as Chairman of the Board of PQ while refining industry services veteran Paul J. Ferrall will serve as President of the Eco Services business unit. Affiliates of CCMP Capital, INEOS Capital, and management remain as shareholders of the combined business.

 

Etihad Rail transports 5m tonnes of sulphur granules

April 9, 2016 - Etihad Rail, the developer and operator of the UAE’s $11 billion national railway network, announced that it has transported more than 5.24 million tonnes of granulated sulphur in the first 18 months of Stage One operations for Abu Dhabi National Oil Company (Adnoc), from sources at Shah and Habshan to its point of export at Ruwais.  Equivalent to more than 330,000 truck trips, the transport of granulated sulphur is the workhorse of Etihad Rail’s Stage One, which received approval for commercial operations from the Federal Transport Authority’s (FTA) – Land and Maritime in December 2015.  Two trains depart daily under the current timetable, each carrying 11,000 tonnes of granulated sulphur and capable of reaching a top-speed of 120 kilometres per hour. Etihad Rail is the country’s latest and most robust facilitator of sulphur movement, which is rapidly growing as an integral part of the UAE economy.  Sulphur is a by-product of oil and gas production and Adnoc and its affiliates export tonnes of sulphur.  “Surpassing the 5.24-million-tonne mark with the transport of granulated sulphur is a significant milestone for Etihad Rail and stands as an emblem of our unwavering commitment to facilitating economic connectivity across Abu Dhabi and the UAE,” said Eng. Faris Saif Al Mazrouei, chief executive officer of Etihad Rail.  “Stage One’s continued progress is a testament to the strength of the partnership between Etihad Rail and Adnoc, who are committed to the UAE’s continued economic diversification and stand aligned with Abu Dhabi Economic Vision 2030 and UAE Vision 2021,” Eng. Al Mazrouei added.  Stretching a distance of 264-kilometre, Stage One links the sulphur sources of Shah and Habshan to the export point of Ruwais via the Mirfa depot, which was recently awarded the Estidama 2 Pearl Construction Rating by the Abu Dhabi Urban Planning Council (UPC) for its seven sustainable buildings. Stage One utilises seven state-of-the-art locomotives from US-based Electro-Motive Diesel, with wagons supplied by China’s CSR Corporation.  The multi-billion dollar integrated rail network project, which will span approximately 1,200 kilometres when complete, is undergoing construction in three stages. The UAE will witness the development of a secure railway transportation network capable of transporting large volumes of goods and materials while linking the UAE’s principle centres of population and industry, along with the greater GCC railway network.  Etihad Rail is being developed in line with the core tenets of Abu Dhabi Economic Vision 2030 and UAE Vision 2021, which collectively chart a course for economic diversification through strategic initiatives set to catalyse UAE socio-economic growth.  At full capacity, Stage One of Etihad Rail is slated to transport more than seven million tonnes of granulated sulphur annually.

Smelter Fire Secrecy


April 7, 2016 - A misguided effort to save the reputation of a smelter company during the opening of its state-of-the-art Acid Plant in Tsumeb led to the refusal to confirm the details of an explosion of a furnace that resulted in injuries and a suspension of a supervisor.  The bursting of a copper smelting furnace at the Dundee Smelter three weeks ago was kept under wraps until yesterday to save President Dr Hage Geingob the embarrassment before he opened the Dundee Acid Plant yesterday, 6 April.  The copper smelter furnace burst on 13 of March and the company’s fire brigade and that of the town’s municipality were mobilised to extinguish the raging sulphuric acid-fueled fire. In the process the fire fighters used water instead of foam and the furnace exploded injuring six people.  The acid spread throughout the premises and started melting the shoes of the fire fighters, which led to six people being hospitalised for inhaling acid fumes, and one was critically injured as the acid ate through the soles of his shoes. Dundee has vehemently denied that the incident ever took place, even in the face of credible information and has gone a step further to suspend the supervisor for safety for alleged negligence a week ago, information that was also smothered.  It could not be established whether the company has reported the incident to the authorities but it must have been an undesirable incident that could have put the safety of working with dangerous and poisonous chemicals in disrepute in the eyes of President Geingob, after a lifeline was thrown to Dundee by Cabinet in 2012.  For the past half a century, Tsumeb has been a health risk caused by local sulphur dioxide (SO2) gas emissions from the Namibian Custom Smelter, until Dundee Precious Metals took over the smelter in 2010. In 2013, after consultation with government the mine was rebranded from the former Custom Smelter to Dundee Smelter with the construction of the acid plant. Dundee took a long-term strategy to bring the smelter to internationally-accepted environmental standards, and in response to government and public concerns about the emissions, they built facilities that capture arsenic emissions and use them to produce sulphuric acid which is a critical component in the mining industry. The plant is designed to reduce sulphur dioxide emissions by 95%.  The state-of-the-art plant was officially inaugurated by President Dr Hage Geingob yesterday. Dr Geingob said that the acid plant came as a result of numerous genuine complaints that the government received from Tsumeb residents over time. “The original complaints were in 2011 that the smelter was emitting arsenic dust which adversely affected the lives of employees and community members. The government heard the complaints and decided to address the problem. The Cabinet at the time tasked the line minister to investigate the matter with support of UNDP, which was concluded in 2012.”  The president continued that problems that were indicated in the report could be solved and there was no need to close the smelter. “Cabinet decided to improve smelter operations to meet Namibian and International standards of modernising infrastructure. Dundee was then entrusted to install modern high technology equipment that ensure the problem of 2011 is comprehensively addressed.“  Dundee chief executive officer and president, Rick Howes said the acid plant project is only the latest initiative in a series of investments made to upgrade the smelter to modern standards. “It costs N$2 billion, and it shows our commitment to improve the quality of life for employees and local people and also reduce the impact the smelter has on environment.“  The sulphuric acid produced is sold to uranium mines and is transported by rail to the coast.http://www.informante.web.na/smelter-fire-secrecy.17547  


Geingob opens N$3 billion sulphuric plant in Tsumeb
 

April 7, 2016 - President Hage Geingob yesterday inaugurated Dundee Precious Metal’s N$3.9 billion sulphuric acid plant in Tsumeb, part of a strategic new business venture for the copper smelting company.  The plant is said to be able to eliminate about 95 percent of toxic emissions pumped into the air by the smelter. The acid plant will capture sulphur dioxide emissions that result from the mineral smelting process and use these to produce sulphuric acid, a critical component in the mining industry.  The investment is expected to ensure there will be no emissions of sulphur dioxide into the air through the furnace stack, particularly over Tsumeb or the work areas of the smelter, which has for many years affected residents in the surrounding areas.  The N$3.9 billion investment in the state-of-the-art acid manufacturing plant is one of the largest direct capital investments in the country, bringing with it modern high technology and equipment of world-class standard.  “It is pleasing to note that our calls for increased beneficiation and value addition in the mining sector are being implemented by investors. The acid produced here will create business opportunities for TransNamib and other companies. These are the types of investments we value, investments that produce positive spillovers into the rest of our economy,” President Geingob said at the event, which was witnessed by Minister of Environment and Tourism Pohamba Shifeta, Minister of Defence Penda ya Ndakolo and Minister of Mines and Energy Obeth Kandjoze, among other high-ranking officials and senior managers.  “Today we can confidently say that Tsumeb Smelter is close to full compliance with Namibian standards, pending the finalisation of the certification process and I expect this process to be concluded expeditiously,” the president further stated.  Geingob also noted that Dundee’s investment is a positive response to the manner in which government continues to support the promotion of investment in the mining sector by creating a stable political environment and a conducive business climate.  Construction started in 2013 with N$2.6 billion having been committed to the construction of the acid plant, while the overall investment in the plant amounts to N$3.9 billion. The acid plant is expected to produce 230 000 to 280 000 tonnes of sulphuric acid per year, which will be contained within the acid plant and transported in approved, safe and secure containers to destinations nationally.  For over 50 years Tsumeb endured unpleasant sulphuric dioxide fumes from the smelter operation, which presented problems in terms of public and occupational health. These concerns led Cabinet to take a decision in 2011 to conduct an investigation into ways to resolve the problem, and this process eventually led to the establishment of an acid plant.  “We saw the challenge and decided to use it as a business opportunity to use these gases to develop new enterprises that would improve the environment. This is further an indication of Dundee’s commitment to improving the environment, investing in the region, as well as creating employment,” said Dundee’s vice president and managing director, Zebra Kaseta.  Kaseta said the project is just one of a series of investments made to upgrade the Tsumeb Smelter to modern standards.

 

Calabrian Corp. to begin public consultation on Timmins sulphur dioxide plant 

 

April 4, 2016 - Calabrian’s application is currently listed with the Ontario Environmental Registry, which is posted online at http://www.ebr.gov.on.ca/ERS-WEB-External. The EBR (Environmental Bill of Rights) reference number is 012-7078.  The application states that Calabrian is seeking compliance approvals and will include the addition of new or historically unapproved sources for all emissions from the sulphur dioxide manufacturing facility producing sulphur dioxide gas which will be condensed to the liquid state for storage and shipment.  The application includes all sources at the facility, including:

- two (2) sequential sulphur dioxide absorbers,
- one (1) cooling tower,
- two (2) natural gas fired boilers,
- natural gas fired comfort heating system and

- diesel fired emergency generator.

Emissions to the atmosphere from this facility include sulphur dioxide, particulate matter and products of combustion, said the application website.  The public consultation period began in mid-March and will continue through to the last week of April. Anyone wishing to comment on the Calabrian application is asked to do so by April 28, 2016.  All comments received before April 28, 2016, will be considered as part of the decision-making process by the Ministry if they are submitted in writing or electronically using the form provided in this notice and reference EBR Registry number 012-7078, said the government website.The website also notes that all comments and submissions received will become part of the public record. Participants will not receive a formal response to your comment, however; relevant comments received as part of the public participation process for this proposal will be considered by the decision maker for this proposal, said the website.  
  

Outotec Awardeda Sulphuric Acid Plant Contract from Boliden Harjavalta

April 1, 2016 - Outotec Oyj
has agreed with the Sweden-based mining and smelting company Boliden on the main design and delivery of proprietary equipment for a sulfuric acid plant to be built in connection with the Harjavalta nickel and copper smelter in Finland. The order has been booked in Outotec’s 2016 first quarter order intake, the value is not disclosed.  The Boliden Harjavalta plant is one of the largest nickel-copper smelters in Europe. The new gas-cleaning and sulfuric-acid-plant solutions designed by Outotec will process off-gas from the smelters into high-grade industrial sulfuric acid. The plant will meet all of the current and planned European environmental requirements through innovative gas cleaning, production of sulfuric acid and highly efficient heat recovery system. In order to recover as much energy as possible, the heat recovery system uses the surplus heat of the SO2 converter and turns it into high-pressure steam. The surplus heat from the drying and absorption section of the acid plant is converted into hot water and then supplied to the adjacent power plant for further use.  The first construction phase of the sulfuric acid plant is expected to be operational in May-June 2018.

Sulphur dioxide levels exceed maximum limit 

March 18, 2016 - The Bay of Plenty Regional Council is investigating recent spikes in sulphur dioxide gas levels recorded by air monitoring equipment located behind the Hewletts Rd industrial area in Mount Maunganui.  Pollution prevention manager Nick Zaman said the monitoring equipment had recorded unacceptably high sulphur dioxide levels on two occasions in recent weeks. "We know there are a number of sulphur dioxide sources in the area, which include industrial plants manufacturing fertilisers and processing chemicals as well as shipping and train activities."  Mr Zaman said the council had asked for monitoring information from local industries and would treat any breaches of resource consents conditions "very seriously".  The maximum upper limit set by National Environmental Standards for sulphur dioxide which must not be exceeded is 570 micrograms per cubic metre of air over a one hour average.  The two verified breaches were above the upper limits, spiking at 628 and 751 micrograms of sulphur dioxide per cubic metre over a one hour average on February 27 and March 5 respectively. The Pollution Prevention Hotline had received 19 complaints relating to this area in the past 12 months.

The Mar Camino solution 

March 15, 2016 - Copper concentrate is the raw material used to produce copper ingots. The copper concentrate also contains sulfur. Dry smelting performed by smelters in Japan like Saganoseki Smelter and Refinery, remove the sulfur content as a byproduct and process it into sulfuric acid.  Conversely, the wet smelting (solvent extraction-electrowinning [SX-EW]) method used to produce copper ingots produces the copper ingots through an electrolytic process from a leach solution obtained by dispersing sulfuric acid on copper ore. Typically this method uses large amounts of sulfuric acid. In Chile, the world’s number one copper producing country, the consumption of sulfuric acid can be very large depending on the global demand for copper.  To address this supply & demand equation the Mar Camino (Sea Road) was launched in 2010 as the world’s only sulfuric acid/copper concentrate ore (bulk) carrier.  The copper concentrate of 30% purity produced from the copper mines of Chile is stowed in the ship’s hold and then shipped mainly to the Pan Pacific Copper (PPC) Saganoseki Smelter & Refinery in Oita Prefecture. The by-product concentrated sulfuric acid produced in the dry smelting process is loaded in a special-purpose tank and shipped back to Chile, where it is again used in a smelting process at the copper mine or sold.With “freight” for the otherwise empty backhaul, the dual purpose Mar Camino thus reduces logistical costs. 

 

Technip to provide Dorr roaster system for KGHM’s Polish copper smelter project

 

February 16, 2016 - Technip has been selected to provide its Dorr Oliver FluoSolids roaster system for Poland-based mining company KGHM's Glogow I copper smelter optimisation project.  The 480t per day system will include the roaster, dry concentrate feeder and calcine cooler, and in-bed steam coils for cogeneration of electricity.  These components will remove organic carbon and sulphide sulphur from copper concentrate, reduce smelter emissions and improve copper production at the site.  Under the contract, Technip will also provide erection supervision, commissioning, and startup, as well as training assistance to KGHM.  Scheduled for completion in 2017, the project will be carried out by Technip's operating centre in Claremont, California, US.  Technip Stone & Webster Process Technology president Stan Knez said: "Technip's extensive experience in roasting technology along with our proven ability to meet a demanding schedule makes us uniquely qualified for this important project."  The Glogow copper smelter produces cathode copper as well as silver, gold, and concentrates of platinum group metals.  Construction of the refinery began in 1968 and was commissioned in July 1971. Production capacity during that period was 160,000t of electrolytic copper per year.  Technip recently installed the system at the Koniambo Nickel in New Caledonia and Vale's Copper Cliff smelter in Ontario, Canada.

 

Gecko’s Big Ambitions

February 16, 2016 - Gecko Namibia plans to establish the industrial park at Mile 16 between Swakopmund and Wlotzkasbaken. In August 2012, Cabinet decided to allocate 700 hectares of land to Gecko Namibia for the envisaged Vision Industrial Park (VIP). However, the 99-year lease agreement has not been signed yet. “The contract draft was submitted to the government for review and we await feedback,” said Pine van Wyk, MD of the Gecko Group. “The VIP chemical projects are dependent on a large uranium industry of at least four running mines. The Fukushima event caused delays in this development with Areva on care and maintenance and still a very low uranium price,” Van Wyk said. The industrial park entails a port, a desalination plant, a sulphuric acid plant, a soda ash  and bicarbonate soda plant and a caustic soda and phosphoric acid plant. Another subsidiary, Gecko Chemicals, will be the holding company of the chemical factories planned for the Vision Industrial Park. The uranium mining industry in Namibia currently imports all reagent chemicals required for leaching processes. Gecko intends producing sulphuric acid at its VIP plant from imported materials. Dundee Precious Metals recently constructed its own sulphuric acid plant and will become the first producer and supplier of sulphuric acid in Namibia. Dundee will supply Rössing Uranium with sulphuric acid and also the Tschudi copper mine near Tsumeb. Gecko’s intended acid plant will mainly supply its envisaged phosphate project, as well as uranium mines. Langer Heinrich Uranium (LHU) makes use of the alkaline leach process. It requires large quantities of soda ash, sodium bicarbonate and caustic soda as reagents. All of these chemicals are presently imported. Manufacturing of these chemicals can be achieved by using local raw materials such as sea salt and marble, according to Gecko.

Abuse of dominant position – commission issues statement of objection 

February 11, 2106 - In November 2015 the Competition Protection Commission issued a statement of objection against Aurubis Bulgaria AD and Aurubis AG. Based on its preliminary findings, the commission accused Aurubis of abuse of its dominant position in the Bulgarian market for the production and sale of sulphuric acid. The commission accused Aurubis of selling the acid at unjustifiably high prices and thereby discriminating against its Bulgarian customers in favour of international clients.  The commission began its investigation in 2013 following a claim brought by Agropolychim AD against Aurubis for abusing its dominant position as a sulphuric acid producer, and against Aurubis and KCM AD (Plovdiv) – a leading producer of non-ferrous and precious metals in Southeast Europe and the Black Sea Region – for concerted practices aimed at sharing the markets for the sale of sulphuric acid.  At the beginning of the investigation the commission conducted a dawn raid at Aurubis' offices in Pirdop. During the raid, the commission seized electronic, digital and forensic evidence from computer hard drives. Aurubis objected that copies of certain emails between the company and its external lawyers should not be reviewed by the commission as relevant evidence because they were subject to legal privilege. Thus, the commission had no right to request non-confidential versions of the emails to be submitted. Nevertheless, the commission issued a ruling by which, among other things, it accepted that the emails were business secrets and Aurubis was obliged to provide the commission with non-confidential versions in order to assess whether they were privileged. Aurubis objected to the ruling before the Supreme Administrative Court.  The appeal was considered impermissible because it was brought against an act of the commission, which alone could not be appealed before the court. According to the court, the commission's ruling, that certain information provided by the parties to the investigation did not qualify as a business secret, could be appealed separately. However, the court concluded that the commission's assessment of whether the evidence was relevant to the investigation and whether it was privileged could be appealed as part of the commission's final decision only.  The investigation is in its second phase. Aurubis can oppose the statement of objection and propose commitments, and has the right to be heard by the commission in an open hearing session. No time limit is envisaged for completion of the investigation.

King Mohammed VI Inaugurates MAD 6.1 billion OCP Projects 

February 1, 2016 - King Mohammed VI inaugurated, Monday at the Jorf Lasfar industrial complex, a fertilizer plant dedicated to the African Market (Africa Fertilizer Complex) and the first stage of a seawater desalination plant for an overall budget of 6.1 billion dirhams.  Initiated by Morocco’s Office Cherifien de Phosphate (OCP), these large-scale projects represent a new embodiment of the Sovereign’s commitment to south-south cooperation, and his will to support OCP innovation and sustainable development initiatives, accompany its industrial strategy and consolidate Morocco’s leadership in the global phosphates market.  Africa fertilizer Complex, which was achieved upon the instructions of King Mohammed IV, aims to accompany the growth of African markets through continued and regular supply of fertilizers (DAP/MAP/NPK).  The new plant, which required a budget of 5.3 billion dirhams, consists of a Sulfuric acid plant (1.4 million tons per year), a phosphoric acid plant (450.000 tons per year), a fertilizer plant (one million tons of DAP per year), and a 62-megawatt solar station, and up to 200,000 tons of fertilizers storage infrastructure.  This mega project encourages technological and environmental innovation in sulfuric acid production through a 10 MW electric energy gain and an important reduction in seawater consumption. The sulfur dioxide (SO2) waste was reduced three times compared to international norms.  The seawater desalination plant, which is part of OCP’s “Water” strategy, aims to meet the additional needs created by the development of Khouribga-Jorf Lasfar platform without additional demand for conventional water.  The plant, which will be built in three stages, will reach an annual production of 75 million cubic meters.  These infrastructure projects reaffirm Morocco’s willingness to build efficient, productive and credible relations with African countries.  They will enable Morocco to have smart leadership on world phosphate market based on the parameters of productivity, profitability and more importantly, sustainability.