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Sulphuric Acid on the WebTM Technical Manual DKL Engineering, Inc.

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Instrumentation - Temperature
August 22, 2002

Introduction
Thermocouples
Resistance Thermometry
Thermowells
        Thermowell Materials
        Length
        Installation


Introduction

There are many types of temperature instruments that can be used to indicate or measure process temperatures; thermocouples, radiation and optical pyrometry, resistance thermometry, filled-system thermometer, liquid-is-glass thermometers, bimetal thermometers, pyrometric cones and temperature-sensitive crayons and paints.

Of these many methods, only three are typically used in acid plant design for temperature measurement; thermocouples, resistance thermometry and bimetal thermometers.

Thermocouples

When the two junctions of an electric circuit having two different materials as wires are at different temperatures, a potential will exist at the terminals in an open circuit.   If the circuit is closed, a current will flow.  The magnitude of the potential depends on the materials used and the temperature difference between the hot (or measuring) junction and the cold (or reference) junction.  This principle is used in thermocouples to measure temperature.

There are seven standard material combinations used in thermocouples.  Each combination is given a letter designation (i.e. type B, E, J, K, R, S, T).  Type S is the international standard for purposes of calibration and comparison.

Type J thermocouples will cover the majority of applications in sulphuric acid plants.  Higher temperature applications (i.e. sulphur furnace, regen. furnace) will use a type K thermocouple.

Type Nominal Temperature Range Material Identification
B 0 to 1820°C Platinum-30% Rhodium vs. Platinum-6% Rhodium
E -270 to 1000°C Nickel-10% Chromium vs. Copper-Nickel
J -210 to 760°C Iron vs. Copper-Nickel
K -270 to 1372°C Nickel-10% Chromium vs. Nickel-5% Aluminum, Silicon(a)
R -50 to 1768°C Platinum-13% Rhodium vs. Platinum
S -50 to 1768°C Platinum-10% Rhodium vs. Platinum
T -270 to 400°C Copper vs. Copper-Nickel

(a) Silicon, or aluminum and silicon may be present in combination with other elements.

Resistance Thermometry

All pure metals increase in electrical resistance with rise in temperature in a repeatable and predictable manner.  A resistance temperature detector (RTD) is simply a length of appropriate wire, suitable insulated, would on a form, adjusted to a definite resistance at a specified temperature and contained in a protecting tube.  A small electrical current passing through the detector produces and output signal proportional to the temperature.  Accuracy depends on a suitable power source and proper selection of precision bridge resistors which do not vary with temperature.

RTD's are generally used in measuring temperatures in rotating equipment (ie. bearings, electric motors, etc).

Bimetal Thermometers

When a composite metal strip consisting of two pieces of different metals or alloys welded together is heated, the differential expansion of the metals causes the strip to bend.  This principle is use in dial thermometers.  In sulphuric acid plants, bimetal thermometers will be used where only local display of temperature is required.

Thermowells

A thermowell is a pressure-tight, leak-free receptacle adapted to receive a temperature element and provided with external threads or other means for pressure-tight, leak-free attachment to a vessel.  The thermowell will also protect the temperature element from the process fluid which may be corrosive.

Thermowell Materials

A variety of materials are use for thermowells depending on the conditions of service.  The most common materials and their application to sulphuric acid plants are given in the following table.

Process Fluid Material Remarks
Sulphuric Acid (90-100% H2SO4) Alloy 20  
Oleum (0-30%) 304 or 316 SS  
Weak Acid (0-15% H2SO4) 304 or 316 SS w/tantalum sheath
Alloy C-276
Material selected depends on exact composition of weak acid including HF and HCl
Cooling Water 304 or 316 SS  
Steam 304 or 316 SS  
SO2 Gas, wet 304 or 316 SS w/tantalum sheath
Alloy C-276
Material selected depends on exact composition of weak acid including HF and HCl
SO2 Gas, dry (< 650°C) 316 SS  
SO2 Gas (> 650°C) Ceramic  

Length

In most cases, the thermocouple/thermowell should be reach to the mid-point of pipe, duct or vessel.  Shorter lengths may be used where the thermowell would be unsupported and there is a risk of it breaking or putting too much stress on the nozzle.

Installation

The installation of the thermowell will vary depending on the service and the material of the process line.

Service Typical Connection
Gas Ducting (metal) 1½" 150# R.F.
FRP Equipment and Ducting 1½" 150# F.F.
Contact Section Equipment
(i.e. Converter, Heat Exchangers)
2" 150# R.F.
Weak Acid Piping (FRP) 1½" 150# R.F.
Utility Piping 1½" 150# R.F.
Acid Piping - Stainless Steel 1½" 150# R.F.
Acid Piping (Ductile Iron) size of smallest branch connection
(ie. 10" main line, smallest branch connection available 4" on standard 10"x10"x4" tee)