Knowledge for the Sulphuric Acid Industry
Sulphuric Acid on the Web
Introduction
General
Equipment Suppliers
Contractor
Instrumentation
Industry News
Maintenance
Acid
Traders
Organizations
Fabricators
Conferences
Used
Plants
Intellectual
Propoerty
Acid
Plant Database
Market
Information
Library
Technical Manual
Introduction
General
Definitions
Instrumentation
Plant Safety
Metallurgial
Processes
Metallurgical
Sulphur Burning
Acid Regeneration
Lead Chamber
Technology
Gas Cleaning
Contact
Strong Acid
Acid Storage
Loading/Unloading
Transportation
Sulphur
Systems
Liquid SO2
Boiler Feed Water
Steam Systems
Cooling Water
Effluent Treatment
Utilities
Construction
Maintenance
Inspection
Analytical Procedures
Materials of Construction
Corrosion
Properties
Vendor Data
DKL Engineering, Inc.
Handbook of Sulphuric Acid Manufacturing
Order
Form
Preface
Contents
Feedback
Sulphuric Acid
Decolourization
Order Form
Preface
Table of Contents
Process Engineering Data Sheets - PEDS
Order
Form
Table of Contents
Introduction
Bibliography of Sulphuric Acid Technology
Order Form
Preface
Contents
Analytical Procedures - Arsenic in Acid
December 19, 2002
Introduction Equipment Reagents Procedure Calculation |
Associated Links |
There are few methods to analyse arsenic, but the fastest and most
reliable system is determination by Atomic Absorption as volatile hydride. The
sample is treated with potassium persulphate and sulphuric acid in order to
oxidize the arsenic to As(V), because in this oxidation state, the volatile
hydride of the element produces a more time-constant signal.
The reduced form of arsenic, As(III), produces a stronger but more random
signal.
Pour 50 ml of arsenic free water in a 100 ml flask. Add about 1 to 2
grams of acid to be tested (exactly weighed). Add 1 gram of potassium
persulphate pure reagent and 1 ml of hydrochloric acid. Heat on the water-bath
for about 90 minutes to ensure all As(III) is oxidized to AS(V).
Allow the sample to cool for about an hour and make up to the mark. The solution
is ready to be analysed in Atomic Absorption by hydride system evolution.
If possible use a double beam spectrometer equipped with an automatic VHE
system, like the Perkin Elmer MHS 20 or FIA one. Put 1 ml of the sample into the VHE system, add the proper
solutions, as recommended by the instrument instruction manual and read the
absorption peak (or directly concentration) at 193.7 nm. Determine, the arsenic
concentration against previously defined calibration curves.
None