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DKL Engineering, Inc.
Handbook of Sulphuric Acid Manufacturing
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Preface
Contents
Steam Systems - Economizers
September 17, 2001
Introduction Steaming Gas Temperature Control Parallel vs. Series Boiler Feed Water Preheating Gas Dew Point Temperature Tube Wall Temperature |
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Economizers
serve to improve the efficiency of plant operation by recovering waste heat from
the gas stream an putting the energy into generating steam.
If steaming occurs in an
economizer not designed to generate steam, water hammer and vibration may
result. These problems can be avoided by not designing for too close an
approach to the saturation temperature in the economizer.
If steaming cannot be
avoided, the economizer can be designed to ensure the steam/water mixture flows
upward through the bundle and into the steam drum. This avoids high points
where the steam can separate from the mixture and give rise to hydraulic
disturbances.
To prevent condensation of
acid on the shellside it is preferable to bypass on the water side to control
the gas exit temperature. Any reduction in gas flow due to gas bypassing
results in a closer temperature approach at the exit of the economizer and
increased chance of condensation. Depending on the degree of
instrumentation and automation, the bypass can either be a manual valve or a
control valve.
In a double absorption plant, economizers can be placed prior to the
Intermediate and Final Absorber Towers to cool the gas before it enters the
towers. When there are more than two economizers a decision must be made
as to whether to place the units in parallel or series with respect to the water
side.
In the example given (ie. double absorption plant) it is preferable to place the
economizers in series on the water side with the boiler feed water entering the
'Final' economizer first and then the 'Inter' economizer. This arrangement
reduces the chance of condensation in the economizers.
Boiler feed water typically leaves the deaerator at 105°C (221°F). At this
temperature there is a strong possibility that the tube wall temperature will be
low enough that condensation will occur on the shell side. The dewpoint of
the gas entering the Intermediate Absorber is expected to be higher than the gas
entering the Final Absorber. In this arrangement the coldest boiler feed
water is first fed through the unit ('Final' economizer) where condensation is
least likely to occur. The boiler feed water leaves the 'Final'
economizers preheated before it enters the 'Inter' economizers. The result
is a higher tube wall temperature in the 'Inter' economizer and condensation of
acid is less likely to occur.
Preheating the boiler feedwater can help reduce the possibility of condensation
on the shell side of economizers by raising the tube water temperature above the
dewpoint of the gas. This can be done in a number of ways such as
increasing the deaerator operating temperature, heat recovery from blowdown,
attemporators, steam desuperheating, etc. These and other techniques are
discussed in more detail in BFW Heating Systems.
The disadvantage of using hotter boiler feed water is a closer temperature
approach at the gas outlet/water inlet of the economizer which increases its
size. However, the size increase can probably be tolerated by the fact
that condensation has been avoided.
There are several techniques that can be used within the economizer itself to
raise the tube wall temperature. The simplest is to design the economizer
as a co-current instead of a countercurrent exchanger. The disadvantage is
the unit is much bigger when designed as a co-current unit rather than a
countercurrent unit.
An alternative is to place a small bank of tubes at the gas inlet in which the boiler feed water is preheated before entering the primary tube bundle in countercurrent flow to the gas.
If process gas is cooled
down far enough, acid will condense from the gas onto the cold surface.
The temperature at which condensation begins is called the dew point
temperature. The dew point of the gas is a function of the partial
pressure of water and sulphur trioxide in the gas. The SO3
in the gas comes as a result of the conversion of SO2
to SO3. Water enters the plant from the
small amount that is not removed in the dry tower or from the combustion of
hydrocarbons in sulphur.
As the partial pressure of either component is raised, the dew point temperature increases. Several methods are available to estimate the dew point of the gas. Unfortunately, the dew points obtained from the different methods may vary by more than 20°C.
Condensation will occur on a cold surface if its temperature is low enough. In an economizer, the section of tubes which sees the coldest gas will be most prone to condensation on the surface of the tube. Because of thermal resistances in the surface films and tube wall, the temperature of the tube surface will be inbetween the temperature of the water and gas. The tube wall temperature should be checked to ensure condensation will not occur.