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Sulphuric Acid on the WebTM Technical Manual DKL Engineering, Inc.

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Sulphuric Acid on the Web

Introduction
General
Equipment Suppliers
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Instrumentation
Industry News
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Intellectual Propoerty
Acid Plant Database
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Library

Technical Manual

Introduction
General

Definitions
Instrumentation
Plant Safety
Metallurgial Processes
Metallurgical
Sulphur Burning
Acid Regeneration
Lead Chamber
Technology
Gas Cleaning
Contact
Strong Acid
Acid Storage
Loading/Unloading

Transportation
Sulphur Systems
Liquid SO2
Boiler Feed Water
Steam Systems

Cooling Water
Effluent Treatment
Utilities
Construction
Maintenance
Inspection
Analytical Procedures
Materials of Construction
Corrosion
Properties
Vendor Data

DKL Engineering, Inc.

Handbook of Sulphuric Acid Manufacturing
Order Form
Preface
Contents
Feedback

Sulphuric Acid Decolourization
Order Form
Preface
Table of Contents

Process Engineering Data Sheets - PEDS
Order Form
Table of Contents

Introduction

Bibliography of Sulphuric Acid Technology
Order Form

Preface
Contents

Sulphuric Acid Plant Specifications
 

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Acid Plant Database  January 23, 2017

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Haldor Topsoe WSA Plants - Sulphur Burning

Company Capacity (MTPD) Year Gas Source
- - - -

Haldor Topsoe WSA Plants - Metallurgical

Company Capacity (MTPD) Year Gas Source
Votorantim Metais 239 2012 Lead smelter (batch operation)

Molibdenos y Metales S.A. (Molymet)
Mejillones

170 2010 MoS2 roaster
China Molybdenum Metallic Material Company Ltd. 75 2009 MoS2 roaster

Molibdenos y Metales S.A. (Molymet)
Santiago

170 2007 Molybdenum (MoS2) roaster
ZAO Karabashmed 1,140 2005 CuS smelter
OAO Kazzinc 895 2004

PbS sinter plant
ZnS roaster

Molymex S.A. de C.V. 65 2001 Molybdenum (MoS2) multiple hearth roaster
Zhuzhou Smelter 525 2001 PbS sinter plant

Molibdenos y Metales S.A. (Molymet)
Santiago

104 1993 Molybdenum (MoS2) roaster

Metaleurop S.A.
(Shutdown)

380 1993 PbS sinter plant Metaleurop-France.JPG (51096 bytes)
SADACI N.V. 106 1990 Molybdenum (MoS2) roaster

Metals & Powders Trollhättan AB
(Shutdown)

20 1986 Molybdenum (MoS2) roaster,12,000 Nm3/h

Haldor Topsoe WSA Plants - Viscose Production

Company Capacity (MTPD) Year Gas Source
P.T. Indo Bharat Rayon 62 2010 H2S/CS2 gas, sulphur
Kelheim Fibres GmbH 204 2007 H2S/CS2 gas, sulphur
Lenzing (Nanjing) Fibers Co., Ltd. 303 2007 H2S/CS2 gas, sulphur
Lenzing AG 140 2004 H2S/CS2 gas, sulphur
PT South Pacific Viscose 120 1993 Boiler flue gas, H2S/CS2 gas, sulphur

Haldor Topsoe WSA Plants - Refineries

Company Capacity (MTPD) Year Gas Source
PetroPeru 460 2014 Amine wash after HDS unit including SWS gas
H2S gas and NH3 gas
ConocoPhillips Rivers Terminalnew2.gif (111 bytes) - 2014 H2S gas
Ningbo Haiyue New Material Co. Ltd.new2.gif (111 bytes) - 2013 Sulphuric acid alkylation
OJSC Kuibyshev Refinery 34 2013 -
ConocoPhillips Whitegate Refinery 30 2012 H2S gas
Naftna Industrija Srbije  13.5 2012 Sulphuric acid alkylation and amine wash after HDS unit
Spent acid and H2S gas
Staatsolie Maatschappij 33 2012

Amine wash after HDS unit including SWS gas
H2S gas and NH3 gas

Petrobras RNEST
Pernambuco, Brazil

750 2012

Heavy fuel oil/ petro coke-fired steam/power plant
Flue gas, H2S gas and SWS gas, sulphur

Petrobras RNEST
Pernambuco ,Brazil

750 2012

Heavy fuel oil/ petro coke-fired steam/power plant
Flue gas, H2S gas and SWS gas, sulphur

CJSC Nizhnekamsk Refinery OJSC Taneco
Nizhnekamsk, Tatarstan, The Russian Federation

55 2012

Sulphuric acid alkylation and amine wash after HDS unit
Spent acid and H2S gas

JSC Lukoil
Perm Oil Refinery
Perm, The Russian Federation

127 2011

Sulphuric acid alkylation and amine wash after HDS unit Spent acid and H2S gas

OAO “Novo-Ufimsky Oil Refinery”
Ufa, The Russian Federation

132 2011

Sulphuric acid alkylation and amine wash after HDS unit Spent acid and H2S gas

OOO “Lukoil-Nizhegorodnefteorgsintez”
Kstovo (Nizhny Novgorod), The Russian Federation

81 2010

Claus plant
Claus tail gas + 92% H2S gas

AB Mazeikiu Nafta
Mazeikiai, Lithuania

380 2010

Heavy oil fired steam and power plant
Flue gas, H2S gas

Lukoil Neftochim Bourgas AD

87 2009

Sulphuric acid alkylation and amine wash after HDS unit Spent acid + 98% H2S gas

OAO YUKOS-Angarsk Petrochemical Co.
Angarsk, The Russian Federation

180 2009

Amine wash after HDS unit
H2S gas

OMV Refining & Marketing GmbH
Schwechat, Austria

- 2007

Heavy oil fired steam and power plant
Flue gas

P.O. NAFTAN (JSC Naftan Company)

235 2007 Amine wash after HDS unit
H2S gas

OAO Tyumenskaya Neftyanaya Kompaniya
Ryazan Oil Refinery 

405 2006

Amine wash after HDS unit
86% H2S gas + SWS gas

OAO Tyumenskaya Neftyanaya Kompaniya
Ryazan Oil Refinery 

330 2005

Sulphuric acid alkylation and amine wash after HDS unit Spent acid + 86% H2S gas

OSC Slavneft-Yaroslav-Nefteorgsintez
Yaroslavl, The Russian Federation

260 2005

Sulphuric acid alkylation and amine wash after HDS unit Spent acid + 86% H2S gas

P.O. NAFTAN (JSC Naftan Company)

223 2004

Amine wash after HDS unit
H2S gas

OSC Slavneft-Yaroslav-Nefteorgsintez
Yaroslavl, The Russian Federation

47 2002

Sulphuric acid alkylation and amine wash after HDS unit Spent acid + H2S gas

Irving Oil Limited 278 2001

Sulphuric acid alkylation and amine wash after HDS unit
Spent acid + 87% H2S gas

Irving Oil Limited 40 2001

Claus plant
0.7% H2S gas + 0.3% SO2 gas (tail gas)

Yueyang Xingchang Petrochemical Co., Ltd. for Changling Oil Refinery Ltd.
Yue Yang, Hunan Province, People’s Republic of China

214 2001

Amine wash after HDS unit
H2S gas + sulphur

Formosa Petrochemical Corp.
Mailiao, Taiwan

220 2000

Sulphuric acid alkylation and amine wash after HDS unit Spent acid + H2S gas

Agip Petroli SpA
Gela, Italy

490 1999

Heavy fuel oil/petro coke-fired steam/power plant
Flue gas

JSC Lukoil
Permnefteorgsintez
Perm Oil Refinery
Perm, The Russian Federation

207 1999

Amine wash after HDS unit
80-90% H2S gas

Slovnaft Oil Refinery
Bratislava, Slovakia

50 1999

Sulphuric acid alkylation
Spent acid + sulphur

GS Caltex Oil Corp., Ltd.
Yocheon, Republic of Korea

209 1995

Residue fluid catalytic Cracking
SO2 gas

OAO Tyumenskaya Neftyanaya
Kompaniya, Ryazan Oil Refinery

155 1994

Amine wash after HDS unit
70-90% H2S gas

OAO Tyumenskaya Neftyanaya
Kompaniya, Ryazan Oil Refinery 

155 1993

Amine wash after HDS unit
70-90% H2S gas

Haldor Topsoe WSA Plants - Coking

Company Capacity (MTPD) Year Gas Source

Ansteel Co. Ltd.
Anshan, Liaoning Province, People’s Republic of China

36 2011

Carbonate wash of coke oven gas
H2S gas

Henan Shuncheng Group Coal and Coking Co., Ltd.
Anyang County, Henan Province, People’s Republic of China

63 2011

Carbonate wash of coke oven gas
H2S gas

Baoshan Iron & Steel Co., Ltd.
Meishan Works, Nanjing, People’s Republic of China

26 2011

Carbonate wash of coke oven gas
H2S gas

Tianjin Ironworks
Gengle, Shexian, Hebei Province, People’s Republic of China

39 2010

Carbonate wash of coke oven gas
H2S gas

Panzhihua Iron & Steel Co. Ltd.
Panzhihua, Sichuan Province, People’s Republic of China

33 2010

Carbonate wash of coke oven gas
H2S gas

Tangshan Jiahua Coking & Chemical Co. Ltd. Tangshan, Hebei Province, People’s Republic of China

47 2010

Ammonia scrubbing of coke oven gas
H2S gas

Petrochemia-Blachownia S.A.
Kedzierzyn-Kozle, Poland

25 2010

BTX refining
Spent acid

Chongqing Iron & Steel Co. Ltd.
Chongqing, People’s Republic of China

2 x 52 2009

Carbonate wash of coke oven gas
H2S gas

Shaoguan Iron & Steel Co.
Shaoguan, Guangdong Province, People’s Republic of China

45 2009

Carbonate wash of coke oven gas
H2S gas

J.S.C. Krivorozhstal
Krivoi Rog, Ukraine

212 2009

Carbonate wash of coke oven gas
H2S gas

Handan Iron & Steel
Handan, Hebei Province, People’s Republic of China

51 2009

Carbonate wash of coke oven gas
H2S gas

Baoshan Iron & Steel Co. Ltd.
Meishan Works
Nanjing, People’s Republic of China

61 2008

Carbonate wash of coke oven gas
H2S gas

Taiyuan Iron & Steel (Group) Co., Ltd. (“TISCO”) Taiyuan, People’s Republic of China

50 2008

Carbonate wash of coke oven gas
H2S gas

Avdeevka Coke Chemical Work
Avdeevka, Ukraine

109 2002

Carbonate wash of coke oven gas
H2S gas

Avdeevka Coke Chemical Work
Avdeevka, Ukraine

86 2002

Carbonate wash of coke oven gas
H2S gas

Trinecké železárny a.s.
Trinec, Czech Republic

12 1999

Carbonate wash of coke oven gas
H2S gas

VFT Belgium N.V.
Zelzate, Belgium

4 1999

BTX refining
H2S gas and Hydrocarbons

ARAL Aromatics GmbH
(previous Redestillations-gemeinschaft GmbH)
Gelsenkirchen, Germany

8 1997

BTX refining
H2S gas and Hydrocarbons

Bitmac Ltd.
Llanwern, Wales, United Kingdom
(Shutdown)

11 1995

BTX refining
Spent acid

OCI Company Ltd.
(previous POSCO Chemical Co., Ltd.)
Tongkwangyang, Republic of Korea

4 1995

BTX refining
H2S gas and Hydrocarbons

Saarbergwerke AG
Fürstenhausen, Germany

30 1991

Carbonate wash of coke oven gas
50-70% H2S gas

Association Coopérative Zélan-daise de Carbonisation S.A.
Sluiskil, The Netherlands

18 1990

Carbonate wash of coke oven gas
50-70% H2S gas

Haldor Topsoe WSA Plants - Gasification

Company Capacity (MTPD) Year Gas Source

Henan Jinkai Group
Kaifeng, Henan Province, People’s Republic of China

120 2012

Methanol wash
H2S gas

Inner Mongolia Donghua Energy Co. Ltd.
Inner Mongolia Province, People’s Republic of China

140 2012

Methanol wash after coal gasifier, plus NH3 gas
H2S gas

Yunnan Xianfeng Chemical Industry Co., Ltd.
Yunnan Province, People’s Republic of China

130 2012

Methanol wash after coal gasifier
H2S gas

Yankuang Xinjiang Coal Chemical Co., Ltd.
Urumqi, Xinjiang Province, People’s Republic of China

90 2011

Methanol wash after coal gasifier, plus NH3 gas
H2S gas

Shaanxi Shanhua Fertilizer Co. Ltd.
Shaanxi Province, People’s Republic of China

200 2011

Methanol wash after coal gasifier
H2S gas

Hebi Coal & Electricity Co., Ltd.
Henan Province, People’s Republic of China

46 2011

Methanol wash after coal gasifier
H2S gas

Yunnan Yuntianhua Co. Ltd.
Yunnan Province, People’s Republic of China

86 2010

Rectisol wash after coal gasification
H2S gas

Shanghai Coking & Chemicals Corp.
Shanghai, People’s Republic of China

100 2010

Methanol wash after coal gasifier
H2S gas

Gujarat Narmada Valley Fertilizers Company (GNFC)
Bharuch, India

212 2010

Rectisol wash after coal gasification
H2S gas

China National Coal Development Co. Ltd.
Heilongjiang Coal Chemical Industry (Group) Co. Ltd.
Dalianhe (Harbin)
Heilongjiang Province, People’s Republic of China

23 2010

Methanol wash after coal gasifier
H2S gas

Xinjiang Guanghui New Energy Co., Ltd. Naomaohu
Xinjiang Province, People’s Republic of China

165 2010

Methanol wash after gasifier
H2S gas

Tianjin Soda Plant of Tianjin Bohai Chemical Ind. Co., Ltd.
Tianjin, People’s Republic of China

55 2010

Methanol wash after coal gasifier
H2S gas

Sasol Synfuels (Pty) Ltd.
Secunda, South Africa

345 2009

Rectisol wash after coal gasification
H2S gas

Yunnan Riches Chemical Industry Co. Ltd.
Kaiyuan, Yunnan, People’s Republic of China

83 2008

Methanol wash after coal gasifier
H2S gas

Liuzhou Chemical Industry Co., Ltd.
Liuzhou, People’s Republic of China

50 2006

Methanol wash after coal gasifier
H2S gas

Shanghai Coking & Chemicals Corp.
Shanghai, People’s Republic of China

40 2005

Amine wash after coal gasifier
H2S gas

Sokolovská Uhelná A.S.
(prev. Palivovy Kombinat 25. unor)
Vresova, Czech Republic

106 1993

Rectisol wash after lignite gasifier
H2S gas

NESTE OXO AB
Stenungsund, Sweden

11 1990

Amine wash after heavy oil gasification
2-7% H2S gas

SUPRA AB
Köping, Sweden

17 1980

Amine wash after heavy oil gasification
10-15% H2S gas

SUPRA AB
Kvarntorp, Sweden

17 1980

Amine wash after heavy oil gasification
10-15% H2S gas

Haldor Topsoe WSA Plants - Miscellaneous

Company Capacity (MTPD) Year Gas Source

Bluestar Adisseo (Nanjing) Co. Ltd.
Jiangsu Province, People’s Republic of China

137 2012

Methionine production
Gas and liquids with H2S, CS2, MMP etc.

Undisclosed client
Middle East

11 2012

Organic synthesis plant
Spent sulphuric acid with high organic content

Holliday Pigments Limited (Shutdown)
Hull, United Kingdom

49 1999

Pigments manufacture
SO2 gas

Asahi Chemical Industry Co., Ltd.
Kawasaki, Japan

200 1993

Methyl Methacrylate (MMA) production
Ammonium sulphate and sulphuric acid

Rockwool Lapinus B.V.
Roermond, The Netherlands

5 1992

Melting furnace
SO2 gas

I/S NEFO
Vodskov, Denmark

220 1991

Bituminous coal-fired 300 MW power plant
Flue gas

Ohio Edison Co.
Niles, Ohio, USA
(US Department of Energy Clean Coal Technology II Programme)

34 1991

Bituminous coal-fired 35 MW power plant
Flue gas

 

Company Capacity Year Gas Source
China National Blue Star 300 MTPD 2010 Acid gases from refinery gasifier and methionine plant
300 MTPD 2010
Hunan Zhuzhou Smelter 30000 MTPA 2002 Lead Sinter Machine
Petrom 100 MTPD 2006 Alkylation Spent Acid